Library/Organic Chemistry: Complete Course from Bonding to Reaction Mechanisms/Lesson 67 of 168

Grignard Reagents

14:09
Chad's Prep
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Course Contents

  1. 1Drawing Lewis Structures24:19
  2. 2Formal Charge7:08
  3. 3Valence Bond Theory and Hybridization26:04
  4. 4Molecular Orbital Theory22:47
  5. 5Polarity: Polar vs Nonpolar12:58
  6. 6Intermolecular Forces and Ranking Boiling Points32:50
  7. 7Condensed Structures12:27
  8. 8Bond-Line Structures26:44
  9. 9Identifying Functional Groups23:42
  10. 10Resonance Structures41:58
  11. 11Acids and Bases: Definitions, pKa and Acid Strength14:38
  12. 12Ranking Acids and Bases35:47
  13. 13Naming Alkanes (IUPAC Nomenclature)34:45
  14. 14Naming Complex Substituents23:17
  15. 15Naming Bicyclic Compounds14:48
  16. 16Drawing Constitutional Isomers21:00
  17. 17Newman Projections13:25
  18. 18Cyclohexane Chair Conformations45:30
  19. 19Constitutional Isomers vs Stereoisomers36:02
  20. 20Assigning R and S Configurations25:23
  21. 21Stereoisomers with Multiple Chiral Centers24:30
  22. 22Fischer Projections13:41
  23. 23Determining Isomeric Relationships12:54
  24. 24Chirality Without Chiral Centers and Amine Inversion11:54
  25. 25Optical Activity and Specific Rotation16:48
  26. 26Reaction Enthalpy and Bond Dissociation Energy12:29
  27. 27Thermodynamics: Entropy, ΔG and Keq17:55
  28. 28Kinetics of Organic Reactions17:18
  29. 29Nucleophiles, Electrophiles and Intermediates16:09
  30. 30Curved Arrow Pushing19:25
  31. 31SN2 Reactions29:21
  32. 32SN1 Reactions24:45
  33. 33SN1 vs SN221:27
  34. 34Intro to Elimination Reactions7:44
  35. 35E2 Reactions25:54
  36. 36E1 Reactions and E1 vs E215:26
  37. 37SN1 vs SN2 vs E1 vs E214:26
  38. 38Naming Alkenes18:25
  39. 39Intro to Alkene Addition and Markovnikov's Rule8:37
  40. 40Hydrohalogenation of Alkenes9:48
  41. 41Hydration of Alkenes24:19
  42. 42Alcohol Addition to Alkenes7:18
  43. 43Catalytic Hydrogenation of Alkenes8:15
  44. 44Halogenation of Alkenes and Halohydrin Formation13:18
  45. 45Epoxidation and Syn/Anti-Dihydroxylation of Alkenes8:37
  46. 46Predicting Alkene Addition Products6:39
  47. 47Ozonolysis vs Permanganate Cleavage of Alkenes5:28
  48. 48Naming Alkynes6:39
  49. 49Acidity of Terminal Alkynes5:27
  50. 50Alkyne Synthesis8:07
  51. 51Reduction of Alkynes10:37
  52. 52Hydrohalogenation of Alkynes6:08
  53. 53Halogenation of Alkynes2:49
  54. 54Hydration of Alkynes17:31
  55. 55Ozonolysis of Alkynes3:51
  56. 56Acetylide Alkylation3:53
  57. 57Free Radical Halogenation13:54
  58. 58Free Radical Halogenation Mechanism15:46
  59. 59Allylic and Benzylic Bromination with NBS11:18
  60. 60Radical Addition of HBr/ROOR8:17
  61. 61Introduction to Organic Synthesis and Retrosynthesis25:41
  62. 62Common Synthesis Patterns with Alkenes22:36
  63. 63Common Synthesis Patterns with Alkynes26:27
  64. 64Naming Alcohols8:36
  65. 65Properties of Alcohols28:58
  66. 66Synthesis of Alcohols22:06
  67. 67Grignard Reagents14:09
  68. 68Silyl Ether Protecting Groups for Alcohols9:23
  69. 69Substitution Reactions of Alcohols16:34
  70. 70Elimination Reactions of Alcohols18:56
  71. 71Oxidation of Alcohols13:54
  72. 72Organic Synthesis with Alcohols17:04
  73. 73Naming Ethers3:06
  74. 74Synthesis of Ethers5:17
  75. 75Reactions of Ethers9:34
  76. 76Naming Epoxides4:32
  77. 77Synthesis of Epoxides6:59
  78. 78Ring Opening of Epoxides11:13
  79. 79Thiols6:31
  80. 80Sulfides5:34
  81. 81Organic Synthesis with Ethers and Epoxides16:45
  82. 82Introduction to IR Spectroscopy10:57
  83. 83IR Spectra of Carbonyl Compounds6:27
  84. 84Conjugation and Carbonyl Stretching Frequency5:58
  85. 85Interpreting More IR Spectra6:45
  86. 86Introduction to Mass Spectrometry6:19
  87. 87Isotope Effects in Mass Spectrometry6:29
  88. 88Fragmentation of Alkanes, Alkenes and Aromatic Compounds6:20
  89. 89Fragmentation of Alkyl Halides, Alcohols and Amines4:56
  90. 90Fragmentation of Ketones and Aldehydes3:45
  91. 91Introduction to NMR2:46
  92. 92Number of Signals in C-13 NMR4:53
  93. 93Number of Signals in Proton NMR10:38
  94. 94Homotopic, Enantiotopic and Diastereotopic Hydrogens10:16
  95. 95Chemical Shift in C-13 and Proton NMR8:41
  96. 96Integration in Proton NMR1:47
  97. 97Splitting in Proton NMR4:55
  98. 98Interpreting NMR: Example 15:10
  99. 99Interpreting NMR: Example 27:43
  100. 100Interpreting NMR: Example 33:54
  101. 101Structure Determination from All Spectra: Example 45:58
  102. 102Structure Determination from All Spectra: Example 58:48
  103. 103Complex Splitting in NMR11:42
  104. 104Conjugated Pi Electrons13:03
  105. 1051,3-Butadiene Pi Molecular Orbitals20:42
  106. 106Allyl System Pi Molecular Orbitals10:27
  107. 1071,3,5-Hexatriene Pi Molecular Orbitals8:25
  108. 108UV/Vis Spectroscopy4:27
  109. 109Conjugated Diene Addition: Kinetic vs Thermodynamic15:32
  110. 110Diels-Alder Reactions46:11
  111. 111Cycloaddition Reactions32:46
  112. 112Electrocyclic Reactions22:33
  113. 113Sigmatropic Rearrangements14:51
  114. 114Naming Benzenes12:56
  115. 115Aromatic vs Antiaromatic vs Nonaromatic35:21
  116. 116Effects of Aromaticity on Reactivity8:34
  117. 117Pi Molecular Orbitals of Aromatic and Antiaromatic Compounds15:39
  118. 118Electrophilic Aromatic Substitution (EAS)23:21
  119. 119Friedel-Crafts Alkylation and Acylation17:42
  120. 120Ortho-Para vs Meta Directors39:57
  121. 121Catalytic Hydrogenation vs Birch Reduction5:03
  122. 122Benzene Side Chain Reactions16:56
  123. 123Nucleophilic Aromatic Substitution (NAS)13:55
  124. 124Retrosynthesis with Aromatic Compounds24:28
  125. 125Naming Ketones and Aldehydes9:52
  126. 126Ketone and Aldehyde Synthesis7:40
  127. 127Nucleophilic Addition: Aldehydes vs Ketones13:17
  128. 128Hemiacetals and Acetals16:57
  129. 129Aldehyde and Ketone Protecting Groups7:28
  130. 130Imines and Enamines26:49
  131. 131Reduction of Ketones and Aldehydes11:21
  132. 132Grignard Addition to Aldehydes and Ketones7:11
  133. 133Wittig Reaction10:37
  134. 134Baeyer-Villiger Oxidation6:17
  135. 135Retrosynthesis with Aldehydes and Ketones23:07
  136. 136Naming Carboxylic Acids and Acid Derivatives10:28
  137. 137Nucleophilic Acyl Substitution31:28
  138. 138Nucleophilic Acyl Substitution Mechanisms13:16
  139. 139Grignard Reagents vs Gilman Reagents5:05
  140. 140Hydride Reduction of Carboxylic Acid Derivatives10:51
  141. 141Acid Halide Synthesis and Reactions5:51
  142. 142Acid Anhydride Synthesis and Reactions4:53
  143. 143Ester Synthesis and Reactions19:23
  144. 144Carboxylic Acid Properties, Synthesis and Reactions13:58
  145. 145Amide Synthesis and Reactions4:44
  146. 146Nitrile Synthesis and Reactions5:44
  147. 147Retrosynthesis with Carboxylic Acids and Derivatives16:58
  148. 148Alpha Hydrogen Acidity, Enolates and Enols16:45
  149. 149Mechanisms of Alpha Substitution Reactions6:22
  150. 150Alpha Halogenation and the Haloform Reaction12:49
  151. 151Alpha Alkylation and the Stork Reaction7:01
  152. 152Aldol Reactions32:18
  153. 153Claisen Condensation Reactions12:15
  154. 154Malonic and Acetoacetic Ester Synthesis16:06
  155. 155Michael Reactions10:34
  156. 156Robinson Annulation8:45
  157. 157Retrosynthesis with Enolates and Enols11:26
  158. 158Naming Amines6:54
  159. 159Basicity of Amines6:28
  160. 160Synthesis of Amines23:00
  161. 161Hofmann and Cope Elimination11:57
  162. 162Sandmeyer Reactions4:11
  163. 163EAS Reactions with Nitrogen Heterocycles8:12
  164. 164Retrosynthesis with Amines18:05
  165. 165Classification of Monosaccharides26:25
  166. 166Reactions of Monosaccharides26:54
  167. 167Disaccharides and Polysaccharides12:54
  168. 168Amino Acids and Proteins1:14:59
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